Steve Rogers / Captain America
Nick Fury
Natasha Romanoff / Black Widow
Alexander Pierce
Bucky Barnes / Winter Soldier
Sam Wilson / Falcon
Maria Hill
Brock Rumlow
Jasper Sitwell
Kate / Agent 13
Peggy Carter
Dr. Arnim Zola
Smithsonian Guard
Jack Rollins
Councilwoman Hawley
Councilman Singh
Councilman Rockwell
Councilman Yen
Senator Stern
Georges Batroc
French Pirate #1
French Pirate #2
Engine Pirate
French Radio Pirate
Skinny Steve
Launch Tech #1
Launch Tech #2
Dr. Fine
SHIELD Interrogator #1
SHIELD Interrogator #2
Scientist #1
Scientist #2
Apple Employee
Com Tech #1
Com Tech #2
Renata
Garcia
Charlie XO
Charlie Weapons Tech
SHIELD Tech
Lead SHIELD Pilot
Senior SHIELD Agent
SHIELD Agent
Strike SGT. #1
Strike SGT. #2
Strike Agent
25ᵗʰ Floor Strike Agent
Scudder
Human Resources Executive
Doctor
Lead EMT
CIA Instructor
Capitol Hill Police
FBI Agent
Committee Member
Little Boy in the Smithsonian
Fury Car Voice (voice)
SHIELD Computer (voice)
The Smithsonian Narrator (voice)
Dr. List (uncredited)
SHIELD Agent (uncredited)
Museum Visitor (uncredited)
Baron Wolfgang von Strucker (uncredited)
Wanda Maximoff / Scarlet Witch (uncredited)
Committee General (uncredited)
Pietro Maximoff / Quicksilver (uncredited)
Man on Escalator in Museum (uncredited)